term "thermodynamics" was first used in the publication of
William Rankine
indicates that rate of heat conduction in a direction is proportional to the temperature gradient in that direction
Fourier's Law of Heat Conduction
when a body is resistant to heat, it is called
Thermoduric
boundary of a control volume, which may either real or imaginary
Control Surface
best conductor of heat
Diamond
amount of energy needed to change a given mass of ice to water at constant temperature
Fusion
refers to the portion of the internal energy of a system associated with kinetic energies of molecules
Sensible Energy
second law of thermodynamic, which state that no heat engine can have a thermal efficiency of 100%
Kelvin-Plank Statement
second law of thermodynamic, which state that no device can transfer heat from cooler body to a warmer one without leaving an effect on surroundings
Clausius Statement
if a system at chemical equilibrium is distrubuted by some stress, the system goes to a new equilibrium condition to relieve stress
Le Chatelier's Principle
law that if a process can be written as the sum of several stepwise processes, the enthalpy change the total process equals sum of the enthalphy changes of various steps
Hess Law
formulated the zeroth law of thermodynamics
R.H. Fowler
coined the word "energy"
Thomas Young
the amount of light output in lumens per watts of electricity consumed
Light Efficacy
carnot cycle is composed of how many reversible processes
4
processes involved in Carnot cycle
Two Adiabatic, Two Isothermal
heat transfer by mixing
Convection
during adiabatic, internally reversible process, entropy is
Always Zero
effects of viscosity of liquids
Laminar Flow
invented the barometer
Torricelli
random motion of particles suspended in a fluid is called
Brownian Motion
formation of pockets of gas in a liquid
Cavitation
volume of a definite quantity of dry gas is inversely proporional to pressure provided temperature remains constant
Boyle's Law
bimetallic strip commonly found in home furnace thermostats uses
Thermal Expansion
area of thermodynamics concerned with measuring of thermal properties
Calorimetry
when water is warmed from 0 degrees Celsius to 6 degrees Celsius
Contract first then expand
temperature when water and vapor are in equilibrium with atmospheric pressure
Steam Point
terms refer to amount of heat needed to raise temperature of a unit mass of substance through one degree
Specific Heat
Free Expansion Process
heat rejected is zerowork done is zeroheat supplied is zero
temperature of gas measures the
Average KE of particles in gas
produced mathematical theory of wave mechanics where solution to his equations involve assigning integers to different parameters
Edwin Schrodinger
law of thermodynamics which leads to definition of entropy
Second Law
as temperature goes 0, entropy approaches a constant
Third Law of Thermodynamics
if you open the refrigerator door of a well insulated kitchen, the room will
Heat up
the temperature of drops when they collide and combine without exchanging energy with their environment
Increase
amount of heat required to raise one gram of water by one degree Celsius
Calorie
has greatest influence on overall efficiency of conventional electric generating station burning fossil fuels
Steam temperature at steam turbine inlet
energy of molecular motion in a gas
Temperature
deposition of radiant energy as heat into an absorbing body
Insolation
universe will be at the same temperature everywhere
Entropy Death
laws of thermodynamics often invoked to discredit attempts at perpetual motion
Second Law of Thermodynamics
some heat transfer occurs in a reversible polytropic process (true or false)
True
operates the reverse of the heat engine
Thermal Pump
property of a substance which remains constant if no heat enters of leaves the system
Entropy
phenomenon of melting under pressure and freezing again when pressure is reduced
Regelation
british thermal unit, or BTU is the amount of heat required to raise on pound of this material; one degree fahrenheit
Water
part of a nuclear power plant that prevents thermal pollution of lakes or rivers
Cooling Tower
heat is transferred in extra-terrestrial space by
Radiation
four cycle internal combustion automobile engine operates in this cycle
Otto
a carnot cycle made to run backwards
Refrigerator
internal energy of a perfect gas depends on
Temperature
processes which occur without the addition or withdrawal of heat from surrounding
Adiabatic
in regions where fluid velocity is smaller, the pressure is higher, and vice versa
Bernoulli
diffusion due to thermal motion
Effusion
two different gases have same volume, temperature, and pressure and behave like ideal gases also has identical
Total molecular kinetic energy
cycle which eventually return to first state of the first process
Series Cycle
fixed quantity of mass selected for the purpose of study
Closed System
not all energy received as heat by a heat-engine cycle can be converted into mechanical work, some are also rejected
2nd Law of Thermodynamics
law states that total volume of a mixture of non reacting gases is equal to sum of partial volumes
Azamat's Law
variable that is a function of enthalpy and entropy of the system
Gibb's Free Energy
solubility of gas in a liquid is directly proportional to the partial pressure of the gas above the solution
Henry's Law
minimum amount of radioactive amterial needed to sustain a nuclear chain reaction
Critical Mass
heat engine whose thermodynamic efficiency is greater than that of a carnot device using the same energy reservoir
Perpetual machine of the second kind
reversible process used to form a carnot cycle
Isothermal, Adiabatic
area under the curve on a temperature-entropy diagram
Heat
increasing the temperature of an ideal gas increases
Number of dissociaton products
energy stored in a substance by virtue of the activity and configuration of its molecules and of vibration of atoms within molecules
Internal Energy
known as total heat and heat content at various times in history and represents the useful energy of a substance
Enthalpy
specific property is also
Intensive Property
the quantity of the substance leaving the system is equal to the substance entering the system
Law of Conservation of Mass
pressure of a given quantity of has is held constant
Charles' Law
states that a constant pressure and temperature, the volume of a gas is directly proportional to the number of moles
Avogadro's Law
refers to heat needed to change the temperature of the substances without changing its phase
Sensible Heat
refers to amount of energy absorbed or released during phase-change process
Latent Heat
refers to the transfer of energy between a solid surface and the adjacent fluid that is in motion
Convection
defined as the quantity of heat needed to raise the temperature of one kilogram of water by one degree Celsius
Kilocalorie
what happens to the internal energy of water at reference temperature where enthalpy is zero
Becomes Negative
entropy of all perfect crystalline solids is zero at absolute zero temperature
Third Law of Thermodynamics
what should be the temperature of both water and steam whenever they are present together
One hundred degrees centigrade
radiation emitted must be equal the radiation absorbed at equilibrium
Kirchoff's Law
predicts the approximate molar specific heat at high temperatures from the atomic weight
Law of Dulong Petit
ideal gas whose specific heats area constant
Perfect Gas
state of a simple compressible system is completely specified by two independent intensive properties
State Postulate
theory that heat consisted of a fluid, which could be transferred from one body to another, but not created or destroyed
Caloric Theory
compare adiabatic process to an isentropic process
Both heat transfer is zero and isentropic is reversible
the temperature at which the water vapor in the glue gas begins to condense in a constant pressure process
Dew Point
developed third law of thermodynamics
Walther Nernst
total volume of a mixture of nonreacting gases is equal to the sum of the partial volumes
Amagat's Law
thermal inertia of a thermodynamic system is known as
Entropy
at what temperature is celsius and fahrenheit numerically the same